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Biomarker Focus 15: PBDE 

Polybrominated Diphenylethers (PBDEs) and other flame retardants


Download PDF file

PBDEs have been used as flame retardants over the past two decades, and are globally distributed in the environment. PBDEs accumulate in the food chain and there is a strong concern about the health effects of PBDE exposure.

 

Hovedbilde BMF 15                 Struktur BMF 15


Native PBDEs

Chiron offers single native PBDEs in solution for analytical purposes and as neat material up to gram quantities for toxicological studies. Mixtures are offered according to international methods and on request.

F-PBDEs® Internal standards: An overview of advantages

F-PBDEs® Fluorinated Internal Standards for PBDE analysis are flexible and cost-efficient

Mono- and difluorinated PBDEs are closely similar to the parent PBDEs in terms of physico-chemical properties, and are ideal internal or surrogate standards for GC-MS, GC-ECD, GC-FID and twodimentional GC.

The F-PBDE® internal standards offered by Chiron have several advantages over the more traditionally used 13C isotopes and unlabelled internal standards:

° Cost-efficient. Much cheaper than the 13C isotopes. Useful with electron impact ionization and negative ion chemical ionization.

° Gives one single, pure isotope (F has only one isotope)

° Can be used with GC-ECD detection, 13C can not since they coelute with the native.

° Do not discriminate from the native upon work-up.

° “Designer retention times” (ortho-, meta-, para-F) possible for optimal elution rate.

 

                                    Struktur 2 BMF 15

  

ISO 22032: 2006
Water quality – Determination of selected polybrominated diphenyl ethers in sediments and sewage sludge – Method using extraction and gas chromatography/mass spectrometry.

Native ISO 22032 PBDEs:

 

IUPAC No.

Compound

Cat. No.

 

Cat. No.

 

Tetrabromo:

BDE-47

2,2',4,4'-Tetrabromodiphenyl ether

1962.12-50-IO

1962.12-5MG

Pentabromo:

BDE-99

2,2',4,4',5-Pentabromodiphenyl ether

1967.12-50-IO

1967.12-5MG

 

BDE-100

2,2',4,4',6-Pentabromodiphenyl ether

1968.12-50-IO

1968.12-5MG

Hexabromo:                      

BDE-153

2,2',4,4',5,5'-Hexabromodiphenyl ether

1971.12-50-IO

1971.12-5MG

 

BDE-154

2,2',4,4',5,6'-Hexabromodiphenyl ether

1972.12-50-IO

1972.12-5MG

Heptabromo:                    

BDE-183

2,2',3,4,4’,5’,6-Heptabromodiphenyl ether

1973.12-50-IO

1973.12-5MG

Octabromo:      

BDE-205

2,3,3’,4,4’,5,5’,6-Octabromodiphenyl ether

2647.12-50-IO

-

Decabromo:      

BDE-209

Decabromodiphenyl ether

1811.12-50-IO

1811.12-5MG

 

Multiple components

ISO 22032 PBDEs, 10 µg/mL each in isooctane

S-4535-10-IO

-

 

KIT

ISO 22032 PBDE single components, solutions Kit

8573.8-KIT

-


Solutions of single reference substances and multiple components solution; 50 ěg/mL in isooctane, 1 mL or as neat.


Internal Standards (IS) for ISO 22032: F-PBDEs®
(Electron impact or chemical ionization.)

 

IUPAC No.

IS for BDE No.

Compound

Cat. No.

 

Tetrabromo:             

6-F-BDE-47

47

6-Fluoro-2,2',4,4'-tetrabromodiphenyl ether

2161.12-50-T

 

5,5’-F2-BDE-47

47

5,5'-Difluoro-2,2',4,4'-tetrabromodiphenyl ether

2506.12-50-T

Pentabromo:        

3,6-F2-BDE-99

99,100

3,6-Difluoro-2,2',4,4',5-pentabromodiphenyl ether

2505.12-50-IO

 

3-F-BDE-100

99, 100

3-Fluoro-2,2',4,4',6-pentabromodiphenyl ether

2163.12-50-T

Hexabromo:          

4’-F-BDE-160

153, 154,183

4’-Fluoro-2,3,3’,4,5,6-hexabromodiphenyl ether

1929.12-50-T

Heptabromo:          

3-F-BDE-183

183

3-Fluoro-2,2’3,4,4’,5’,6-heptabromodiphenyl ether

2166.12-50-T

Octabromo:      

2,4’-F2-BDE-199

205, 209

4,6’-Difluoro-2,2’,3,3’,4,5,5’,6’-octabromodiphenyl ether

2167.12-50-T

Nonabromo:          

4’-F-BDE-208

205, 209

4’-Fluoro-2,2’,3,3’,4,5,5’,6,6’-nonabromodiphenyl ether

2168,12-50-T

 

Multiple components

 

Multicomponent Stock Solution of Native  Substances:

ISO 22032 PBDEs, 50 µg/mL each

S-4388-50-IO

 

KIT

 

ISO 22032 F-PBDE® single components, solutions

8574.8.KIT

 
Solutions of single internal standards and multiple components solution; 50 ěg/mL in isooctane or toluene, 1 mL

 

Internal Standards (IS) for ISO 22032 PBDEs
(Negative ion chemical ionization):

 

IUPAC No.

IS for BDE No.

Compound

Cat. No.

 

Tetrabromo:                    

BDE-77

47, 99,100

3,3’,4,4’-Tetrabromodiphenyl ether

1991.12-50-IO

Hexabromo:                   

BDE-181

153, 154,183

2,2’,3,4,4’,5,5’-6-Hexabromodiphenyl ether

2652.12-50-IO


Solutions of single internal standards and multiple component solution; 50 ěg/mL in isooctane, 1 mL.


EPA Method 1614, 2007
Brominated diphenyl ethers in Water, Soil, Sediments and Tissue by HRGC/HRMS

Native PBDEs
Most relevant with respect to EPA Method 1614 (BDEs of primary interest as determined at the 4th Annual Workshop on Brominated Flame Retardants in the Environment, 2002)

 

IUPAC No.

Compound

Cat No.

Cat No. neat

BDE-28

2,4,4’-Tribromodiphenyl ether

1961,12-50-IO

1961,12-5MG

BDE-47

2,2’,4,4’-Tetrabromodiphenyl ether

1962.12-50-IO

1962.12-5MG

BDE-99

2,2’,4,4’,5-Pentabromodiphenyl ether

1967.12-50-IO

1967.12-5MG

BDE-100

2,2’,4,4’,6-Pentabromodiphenyl ether

1968.12-50-IO

1968.12-5MG

BDE-153

2,2’,4,4’,5,5’-Hexabromodiphenyl ether

1971.12-50-IO

1971.12-5MG

BDE-154

2,2’,4,4’,5,6’-Hexabromodiphenyl ether

1972.12-50-IO

1972.12-5MG

BDE-183

2,2’,3,4,4’,5’,6-Heptabromodiphenyl ether

1973.12-50-IO

1973.12-5MG

BDE-209

Decabromodiphenyl ether

1811.12-50-IO

1811.12-5MG

Multiple components

EPA 1614 PBDEs, 20 µg/mL each

S-4390-20-IO

-

KIT

EPA 1614 PBDE single components, solutions

8575.8-KIT

-


Solutions of single reference substances, 50 μg/mL in isooctane ,1 mL or as 5 mg neat

 

Internal Standards (IS) for EPA 1614 PBDEs:

 

IUPAC No.

IS for BDE No.

Compound

Cat. No.

 

Monobromo:              

4’-F-BDE-2

3

3-Bromo-4’-fluorodiphenyl ether

1608.12-50-IO

Dibromo:                    

3’-F-BDE-7

15

3’-Fluoro-2,4-dibromodiphenyl ether

2258.12-50-IO

 

 3’-F-BDE-12

15

3’-Fluoro-3,4-dibromodiphenyl ether

2257.12-50-IO

Tribromo:                 

2’-F-BDE-28

28

2’-Fluoro-2,4,4’-tribromodiphenyl ether

2160.12-50-T

 

4’-F-BDE-25

28

4’-Fluoro-2,3’,4-tribromodiphenyl ether

1926.12-50-IO

 

4’-F-BDE-27

28

4’-Fluoro-2,3’,6-tribromodipheyl ether

1927.12.50-IO

Tetrabromo:             

6-F-BDE-47

47

6-Fluoro-2,2',4,4'-tetrabromodiphenyl ether

2161.12-50-T

 

5,5’-F2-BDE-47

47

5,5'-Difluoro-2,2',4,4'-tetrabromodiphenyl ether

2506.12-50-IO

 

6-F-BDE-66

47

6-Fluoro-2,3’,4,4’-tetrabromodiphenyl ether

2162.12.50-IO

 

4’-F-BDE-69

47

4’-Fluoro-2,3’,4,6-tetrabromodiphenyl ether

1928.12.50-IO

Pentabromo:         

3,6-F2-BDE-99

99, 100

3,6-Difluoro-2,2',4,4',5-pentabromodiphenyl ether

2505.12-50-IO

 

3-F-BDE-100

99, 100

3-Fluoro-2,2',4,4',6-pentabromodiphenyl ether

2163.12-50-T

 

3-F-BDE-119

99, 100

3-Fluoro-2,3’,4,4’,6-pentabromodiphenyl ether

2164.12.50-IO

 

3,5-F2-BDE-119

99, 100

3,5-Difluoro-2,3’,4,4’,6-pentabromodiphenyl ether

2504.12-50-IO

 

5,6-F2-BDE-85

99,100

5,6-Difluoro-2,2’,3,4,4’-pentabromodiphenyl ether

2503.12-50-IO

 

4’-F-BDE-160

138,153,154

4’-Fluoro-2,3,3’,4,5,6-hexabromodiphenyl ether

1929.12-50-T

Heptabromo:           

3-F-BDE-183

183

3-Fluoro-2,2’,3,4,4’,5’,6-Heptabromodiphenyl ether

2166.12-50-T

Nonabromo:           

4’-F-BDE-208

 

209

4’-Fluoro-2,2’,3,3’,4,5,5’,6,6’-nonabromodiphenyl ether

2168.12-50-IO

 

Multiple components

 

EPA 1614 F-PBDEs®

Please inquire

 

KIT: Selection of  8 or  more

single components:

 

EPA 1614 F-PBDEs® single components, solutions

Please inquire


Solutions of single internal standards and multiple component solution, 50 μg/mL in isooctane or toluene, 1 mL or as neat.


Native Lake Michigan PBDEs:

 

IUPAC No.

Compound

Cat. No.

 

Cat. No. neat

 

Tribromo:           

BDE-28

2,4,4’-Tribromodiphenyl ether

1961.12-50-IO

1961.12-5MG

Tetrabromo:       

BDE-47

2,2',4,4'-Tetrabromodiphenyl ether

1962.12-50-IO

1962.12-5MG

 

BDE-66

2,3',4,4-Tetrabromodiphenyl ether

1964.12-50-IO

1964.12-5MG

Pentabromo:       

BDE-85

2,2',3,4,4'-Pentabromodiphenyl ether

1966.12-50-IO

1966.12-5MG

 

BDE-99

2,2',4,4',5-Pentabromodiphenyl ether

1967.12-50-IO

1967.12-5MG

 

BDE-100

2,2',4,4',6-Pentabromodiphenyl ether

1968.12-50-IO

1968.12-5MG

Hexabromo:      

BDE-138

2,2',3,4,4',5-Hexabromodiphenyl ether

1970.12-50-IO

1970.12-5MG

 

BDE-153

2,2',4,4',5,5'-Hexabromodiphenyl ether

1971.12-50-IO

1971.12-5MG

 

BDE-154

2,2',4,4',5,6'-Hexabromodiphenyl ether

1972.12-50-IO

1972.12-5MG

 

Multiple

components

Lake Michigan PBDEs, 10 µg/mL each

S-4391-10-IO

-

 

KIT

Lake Michigan single components, solutions

2653.9KIT

-

 
Solutions of single reference substances and multiple components solution, 50 µg/mL in isooctane, 1 mL or as neat.


Internal Standards (IS) for Lake Michigan PBDEs: “Lake Michigan F-PBDEs ®”   

 

IUPAC No.

IS for BDE No.

Compound

Cat. No.

 

Tribromo:              

2’-F-BDE-28

28

2'-Fluoro-2,4,4'-tribromodiphenyl ether

2160.12-50-T

Tetrabromo:           

6-F-BDE-47

47

6-Fluoro-2,2',4,4'-tetrabromodiphenyl ether

2161.12-50-T

 

5,5’-F2-BDE-47

47

5,5'-Difluoro-2,2',4,4'-tetrabromodiphenyl ether

2506.12-50-IO

 

 6-F-BDE-66

66

6-Fluoro-2,3',4,4'-tetrabromodiphenyl ether

2162.12-50-IO

Pentabromo:       

5,6-F2-BDE-85

85

5,6-Difluoro-2,2',3,4,4'-pentabromodiphenyl ether

2503.12-50-IO

 

3,6-F2-BDE-99

99, 100

3,6-Difluoro-2,2',4,4',5-pentabromodiphenyl ether

2505.12-50-IO

 

3- F-BDE-100

99,100

3-Fluoro-2,2',4,4',6-pentabromodiphenyl ether

2163.12-50-T

Hexabromo:        

4’-F-BDE-160

138, 153, 154

4'-Fluoro-2,3,3',4,5,6-hexabromodiphenyl ether

1929.12-50-T

 

Multiple

components

 

Lake Michigan F-PBDEs®

Includes 2161.12 not 2506.12

Please inquire

 

KIT, 5 or more

of above F-PBDEs®

 

Lake Michigan F-PBDEs®, single components

 

Please inquire

Solutions of single internal standards and multiple components solution, 50 µg/mL in isooctane or toluene, 1 mL.

 
EPA 527.1: 2005      

Drinking water – Pesticides and PBDEs by GC-MS
Determination of selected pesticides and flame retardants in drinking water by solid phase extraction and capillary column gas chromatography/mass spectrometry.

IUPAC No.

Compound

Cat. No.

 

Cat. No. neat

 

PBB-153

2,2’,4,4’,5,5’-Hexabromobiphenyl

3108.12-50-HX

-

BDE-47

2,2',4,4'-Tetrabromodiphenyl ether

1962.12-50-IO

1962.12-5MG

BDE-99

2,2',4,4',5-Pentabromodiphenyl ether

1967.12-50-IO

1967.12-5MG

BDE-100

2,2',4,4',6-Pentabromodiphenyl ether

1968.12-50-IO

1968.12-5MG

BDE-153

2,2',4,4',5,5'-Hexabromodiphenyl ether

1971.12-50-IO

1971.12-5MG

Multiple components

EPA 527 Mix 3, BDE congeners and

hexabromobiphenyl, 50 µg/mL each in isooctane:ethyl acetate

S-4484-50-MX

-


Solutions of single reference substances and multiple components solution, 50 µg/mL in hexane or isooctane, 1 mL or as neat.

 
Native PBDEs; complete list of most relevant PBDEs:

Cat No.

Compound

IUPAC No.

 

8948.12

Phenyl ether

 

 

9124.12-50-IO

2-Bromodiphenyl ether

PBDE-1

 

8747.12-50-IO

3-Bromodiphenyl ether

PBDE-2

 

8748.12-50-IO

4-Bromodiphenyl ether

PBDE-3

 

8748.12-5MG

4-Bromodiphenyl ether

PBDE-3

 

9246.12-50-IO

2,4-Dibromodiphenyl ether

PBDE-7

 

8749.12-50-IO

3,4'-Dibromodiphenyl ether

PBDE-13

Please inquire

8750.12-50-IO

4,4'-Dibromodiphenyl ether

PBDE-15

 

8750.12-5MG

4,4'-Dibromodiphenyl ether

PBDE-15

 

8742.12-50-IO

2,2',4-Tribromodiphenyl ether

PBDE-17

 

8742.12-5MG

2,2',4-Tribromodiphenyl ether

PBDE-17

 

1960.12-50-IO

2,3',4-Tribromodiphenyl ether

PBDE-25

 

1960.12-5MG

2,3',4-Tribromodiphenyl ether

PBDE-25

 

1961.12-50-IO

2,4,4'-Tribromodiphenyl ether

PBDE-28

 

1961.12-5MG

2,4,4'-Tribromodiphenyl ether

PBDE-28

 

2116.12-50-IO

3,3',4-Tribromodiphenyl ether

PBDE-35

 

1962.12-50-IO

2,2',4,4'-Tetrabromodiphenyl ether

PBDE-47

 

1962.12-50-IOx10

2,2',4,4'-Tetrabromodiphenyl ether

PBDE-47

 

1962.12-50-IOx20

2,2',4,4'-Tetrabromodiphenyl ether

PBDE-47

 

1962.12-5MG

2,2',4,4'-Tetrabromodiphenyl ether

PBDE-47

 

1963.12-50-IO

2,2',4,5'-Tetrabromodiphenyl ether

PBDE-49

 

1963.12-5MG

2,2',4,5'-Tetrabromodiphenyl ether

PBDE-49

 

1964.12-50-IO

2,3',4,4-Tetrabromodiphenyl ether

PBDE-66

 

1964.12-5MG

2,3',4,4-Tetrabromodiphenyl ether

PBDE-66

 

1965.12-50-IO

2,3',4',6-Tetrabromodiphenyl ether

PBDE-71

 

1965.12-5MG

2,3',4',6-Tetrabromodiphenyl ether

PBDE-71

 

1990.12-50-IO

2,4,4',6-Tetrabromodiphenyl ether

PBDE-75

 

1990.12-5MG

2,4,4',6-Tetrabromodiphenyl ether

PBDE-75

 

1991.12-50-IO

3,3',4,4'-Tetrabromodiphenyl ether

PBDE-77

 

1991.12-5MG

3,3',4,4'-Tetrabromodiphenyl ether

PBDE-77

 

1966.12-50-IO

2,2',3,4,4'-Pentabromodiphenyl ether

PBDE-85

 

1966.12-5MG

2,2',3,4,4'-Pentabromodiphenyl ether

PBDE-85

 

1967.12-50-IO

2,2',4,4',5-Pentabromodiphenyl ether

PBDE-99

 

1967.12-5MG

2,2',4,4',5-Pentabromodiphenyl ether

PBDE-99

 

1968.12-50-IO

2,2',4,4',6-Pentabromodiphenyl ether

PBDE-100

 

1968.12-5MG

2,2',4,4',6-Pentabromodiphenyl ether

PBDE-100

 

2867.12-50-IO

2,3',4,4',5-Pentachlorobiphenyl ether

PBDE-118

 

1969.12-50-IO

2,3',4,4',6-Pentabromodiphenyl ether

PBDE-119

 

1969.12-5MG

2,3',4,4',6-Pentabromodiphenyl ether

PBDE-119

 

1970.12-50-IO

2,2',3,4,4',5-Hexabromodiphenyl ether

PBDE-138

 

1970.12-5MG

2,2',3,4,4',5-Hexabromodiphenyl ether

PBDE-138

 

1971.12-50-IO

2,2',4,4',5,5'-Hexabromodiphenyl ether

PBDE-153

 

1971.12-5MG

2,2',4,4',5,5'-Hexabromodiphenyl ether

PBDE-153

 

1972.12-50-IO

2,2',4,4',5,6'-Hexabromodiphenyl ether

PBDE-154

 

1972.12-5MG

2,2',4,4',5,6'-Hexabromodiphenyl ether

PBDE-154

 

2652.12-50-IO

2,2',3,4,4',5,6-Heptabromodiphenyl ether

PBDE-181

 

1973.12-50-IO

2,2',3,4,4',5',6-Heptabromodiphenyl ether

PBDE-183

 

1973.12-5MG

2,2',3,4,4',5',6-Heptabromodiphenyl ether

PBDE-183

 

1992.12-50-IO

2,3,3',4,4',5,6-Heptabromodiphenyl ether

PBDE-190

 

1992.12-5MG

2,3,3',4,4',5,6-Heptabromodiphenyl ether

PBDE-190

 

2486.12-50-IO

2,2',3,3',4,4',5,6-Octabromodiphenyl ether

PBDE-195

 

9135.12-50-IO

2,2',3,3',4,4',5,6'-Octabromodiphenyl ether

PBDE-196

 

9136.12-50-IO

2,2',3,3',4,4',6,6'-Octabromodiphenyl ether

PBDE-197

Please inquire

1975.12-50-IO

2,2',3,4,4',5,5',6'-Octabromodiphenyl ether

PBDE-203

 

1975.12-5MG

2,2',3,4,4',5,5',6'-Octabromodiphenyl ether

PBDE-203

 

2647.12-50-IO

2,3,3',4,4',5,5',6-Octabromodiphenyl ether

PBDE-205

 

2647.12-5MG

2,3,3',4,4',5,5',6-Octabromodiphenyl ether

PBDE-205

 

9033.12-50-IO

2,2',3,3',4',5,5',6-Nonabromodiphenyl ether

PBDE-206

Please inquire

9034.12-50-IO

2,2',3,3',4,4',5,6,6'-Nonabromodiphenyl ether

PBDE-207

 

9035.12-50-IO

2,2',3,3',4,5,5',6,6'-Nonabromodiphenyl ether

PBDE-208

Please inquire

1811.12-50-IO

Decabromodiphenyl ether

PBDE-209

 

1811.12-5MG

Decabromodiphenyl ether

PBDE-209

 

2653.9-KIT

Lake Michigan Study’ PBDEs (Kit w/single solutions)

 

 

2665.12-KIT

Other relevant PBDEs (Kit w/single solutions)

(The catalogue p. 153-154)

 

 

3686.28-KIT

PBDE solutions Kit (The catalogue p. 360+ later additions)

 

 

8573.8-KIT

ISO 22032 single components, solutions

 

 

8575.8-KIT

EPA 1614 PBDE single components, solutions

 

 

Solutions of single reference substances, 50 μg/mL in isooctane (1 mL) or as neat.


Bromophenols

Cat No.

Compound

3822.6-K-IP

2-Bromophenol

2383.6-K-IP

4-Bromophenol

3721.6-K-IP

2,3-Dibromophenol

2061.6-K-IP

2,4-Dibromophenol

2470.6-10-5ME

2,5-Dibromophenol

2470.6-K-IP

2,5-Dibromophenol

2472.6-K-IP

2,6-Dibromophenol

8595.6-K-IP

3,4-Dibromophenol

2507.6-K-IP

2,3,4-Tribromophenol

2471.6-K-IP

2,3,6-Tribromophenol

2508.6-K-IP

2,4,5-Tribromophenol

2060.6-K-IP

2,4,6-Tribromophenol

2060.6-5K-5IP

2,4,6-Tribromophenol

2509.6-K-IP

2,3,4,6-Tetrabromophenol

2509.6-10MG

2,3,4,6-Tetrabromophenol

2672.6-50-IO

Pentabromophenol

2384.12-KIT

Bromophenol Kit (1000µg/mL each)

 
Delivered in 1000 µg/mL in isopropanol or 50 µg/mL in isooctane or neat (2509.6)

 

Flame retardants other than PBDEs 

PBBs (polybromobiphenyls)    

Cat No.

IUPAC No.

Compound

3089.12-50-IO

PBB-1

2-Bromobiphenyl

3090.12-50-IO

PBB-2

3-Bromobiphenyl

3091.12-50-IO

PBB-3

4-Bromobiphenyl

3092.12-50-IO

PBB-4

2,2'-Dibromobiphenyl

3093.12-50-IO

PBB-7

2,4-Dibromobiphenyl

3094.12-50-IO

PBB-9

2,5-Dibromobiphenyl

3095.12-50-IO

PBB-10

2,6-Dibromobiphenyl

3096.12-50-IO

PBB-15

4,4'-Dibromobiphenyl

3097.12-50-IO

PBB-18

2,2',5-Tribromobiphenyl

3098.12-50-IO

PBB-26

2,3',5-Tribromobiphenyl

3099.12-50-IO

PBB-31

2,4',5-Tribromobiphenyl

2664.12-50-IO

PBB-29

2,4,5-Tribromobiphenyl

2744.12-35-IO

PBB-30

2,4,6-Tribromobiphenyl

2744.12-50-IO

PBB-30

2,4,6-Tribromobiphenyl

3101.12-50-IO

PBB-38

3,4,5-Tribromobiphenyl

3102.12-50-IO

PBB-49

2,2',4,5'-Tetrabromobiphenyl

3103.12-50-IO

PBB-52

2,2',5,5'-Tetrabromobiphenyl

3104.12-50-IO

PBB-56

2,2',5,6'-Tetrabromobiphenyl

3105.12-50-IO

PBB-80

3,3',5,5'-Tetrabromobiphenyl

3106.12-50-IO

PBB-101

2,2',4,5,5'-Pentabromobiphenyl

3107.12-50-IO

PBB-103

2,2',4,5',6-Pentabromobiphenyl

3108.12-50-HX

PBB-153

2,2',4,4',5,5'-Hexabromobiphenyl

3110.12-50-IO

PBB-155

2,2',4,4',6,6'-Hexabromobiphenyl

3109.12-10-IO

PBB-169

3,3',4,4',5,5'-Hexabromobiphenyl

2677.12-50-IO

PBB-209

Decabromodiphenyl

2679.12-50-IO

PBB

Octabromodiphenyl, techn.

 
Delivered in 50 µg/mL in isooctane or  hexane, 1 mL


Internal Standard (IS) F-PBDEs ®: Complete list
 

Cat. No.

IUPAC No.

Compound

1604.12-50-IO

2-F-PBDE-0

2-Fluorodiphenyl ether

1605.12-50-IO

4-F-PBDE-0

4-Fluorodiphenyl ether

2178.12-K-IO

2,4'-F2-PBDE-0

2,4'-Difluorodiphenyl ether

3620.12-K-IO

3,3'-F2-PBDE-0

3,3'-Difluorodiphenyl ether

1608.12-50-IO

3-F-PBDE-2

3-Bromo-4'-fluorodiphenyl ether

2258.12-50-IO

3'-F-PBDE-7

3'-Fluoro-2,4-dibromodiphenyl ether

2257.12-50-IO

3'-F-PBDE-12

3'-Fluoro-3,4-dibromodiphenyl ether

1926.12-50-IO

4'-F-PBDE-25

4'-Fluoro-2,3',4-tribromodiphenyl ether

1927.12-50-IO

4'-F-PBDE-27

4'-Fluoro-2,3',6-tribromodiphenyl ether

2160.12-50-T

2'-F-PBDE-28

2'-Fluoro-2,4,4'-tribromodiphenyl ether

2161.12-50-T

6-F-PBDE-47

6-Fluoro-2,2',4,4'-tetrabromodiphenyl ether

2506.12-50-IO

5,5'-F2-PBDE-47

5,5'-Difluoro-2,2',4,4'-tetrabromodiphenyl ether (2,2',4,4'-Tetrabromo-5,5'-difluorodiphenyl ether)

2162.12-50-IO

6-F-PBDE-66

6-Fluoro-2,3',4,4'-tetrabromodiphenyl ether

1928.12-50-IO

4'-F-PBDE-69

4'-Fluoro-2,3',4,6-tetrabromodiphenyl ether

2503.12-50-IO

5,6-F2-PBDE-85

5,6-Difluoro-2,2',3,4,4'-pentabromodiphenyl ether (2,2',3,4,4'-Pentabromo-5,6-difluorodiphenyl ether)

2505.12-50-IO

3,6-F2-PBDE-99

3,6-Difluoro-2,2',4,4',5-pentabromodiphenyl ether (2,2',4,4',5-Pentabromo-3,6-difluorodiphenyl ether)

2163.12-50-T

3-F-PBDE-100

3-Fluoro-2,2',4,4',6-pentabromodiphenyl ether

2164.12-50-IO

3-F-PBDE-119

3-Fluoro-2,3',4,4',6-pentabromodiphenyl ether

2504.12-50-IO

3,5-F2-PBDE-119

3,5-Difluoro-2,3',4,4',6-pentabromodiphenyl ether (2,3',4,4',6-Pentabromo-3,5-difluorodiphenyl ether)

1929.12-50-T

4'-F-PBDE-160

4'-Fluoro-2,3,3',4,5,6-hexabromodiphenyl ether

2166.12-50-T

3-F-PBDE-183

3-Fluoro-2,2',4,4',5,5',6-heptabromodiphenyl ether

2167.12-50-T

4',6-F2-PBDE-199

4',6-Difluoro-2,2',3,3',4,5,5',6'-octabromodiphenyl ether

2168.12-50-IO

4'-F-PBDE-208

4'-Fluoro-2,2',3,3',4,5,5',6,6'-nonabromodiphenyl ether

8574.8-KIT

 

ISO 22032 F-PBDE® single components, solutions Kit


Solutions of single reference substances, 50 μg/mL in isooctane or toluene, 1 mL.


Other halogenated flame retardants

Cat No.

Compound

 

 

8751.21-50-T

2,2-Bis[3,5-dibromo-4-(2,3-dibromopropoxy)phenyl]propane

BDBPT

 

8885.24

Bis(2-ethylhexyl)tetrabromophthalate

TBPH

Please inquire

8757.14-50-T

1,2-Bis(2,4,6-tribromophenoxy)ethane

BTBPE

 

8897.3-100MG

2-Bromo-2-nitro-1,3-propanediol

Bronopol

 

2071.7-K-IP

4-Chloro-3-methylphenol

 

 

2670.14-50-CB

Decabromodiphenylethane

 

 

8770.18-50-T

Dechlorane plus

 

 

8898.2-100MG

2,2-Dibromo-2-cyano-acetamide

DBNPA

 

2671.5-50-IP

Dibromoneopentylglycol

 

 

2061.6-10-ME

2,4-Dibromophenol

 

 

2061.6-K-IP

2,4-Dibromophenol

 

 

8883.9

2,3-Dibromopropyl-2,4,6-tribromophenyl ether

DPTE

Please inquire

8884.18-50-T

Ethylene bis(tetrabromophthalamide

 

 

8886.15

2-Ethylhexyl-2,3,4,5-tetrabromobenzoate

PBB

Please inquire

2678.6-50-IO

Hexabromobenzene

 

 

1894.6-50-IO

1,2,3,4,5,6-Hexabromocyclohexane

 

 

1893.12-K-T

1,2,5,6,9,10-Hexabromocyclododecane

HBCD

Racemic mixture

 

1893.12-1G

1,2,5,6,9,10-Hexabromocyclododecane

HBCD

Racemic mixture

On request

8881.8-50-IO

Pentabromoethylbenzene

PBEB

 

2672.6-50-IO

Pentabromophenol

 

 

2673.7-50-IO

Pentabromotoluene

 

 

2674.15-50-IO

3,3',5,5'-Tetrabromobisphenol A

TBBA

 

8887.21-50-T

3,3',5,5'-Tetrabromobisphenol A diallyl ether

 

 

2675.17-50-IO

3,3',5,5'-Tetrabromobisphenol A dimethyl ether

 

 

8771.21

3,3',5,5'-Tetrabromobisphenol A bis(2,3-dibromopropyl) ether

 

 

8772.19

3,3',5,5'-Tetrabromobisphenol A bis(2-hydroxyethyl) ether

 

 

8882.9

2,4,6-Tribromophenylallyl ether

ATE

 

2060.6-K-IP

2,4,6-Tribromophenol

 

 

2676.8-50-IO

Tetrabromophthalic anhydride

 

 

1812.18-50-CY

Tetradecabromo-1,4-diphenoxybenzene

 

 

 

Melamine (triazine)-based flame retardants

 

 

8754.3-1G

Melamine cyanurate

Reflam MCA

 

8755-1G

Melamine micronized

Reflam MA

 

8752-1G

Melamine phosphate

Reflam MP

 

8753-1G

Melamine polyphosphate

Reflam MPP

 

 

Phosphor-Phosphate-based flame retardants

 

 

8798.0-1G

Ammonium polyphosphate (Phase II n>1000)

Reflam APP

 

8764.6

Bis(2,3-dibromopropyl)phosphate

 

 

8764.6-10MG

Bis(2,3-dibromopropyl)phosphate

 

 

8756-100MG

Bisphenol A bis(diphenyl)phosphate,
Rx product of Phosphoric acid trichloride biphenol A and phenol

BDP

 

8738.20-K-IO

Ditolylphenylphosphate - Mixture of o-,m-,p-tolyl isomers

 

 

3967.19-K-IO

Diphenyltolylphosphate - Mixture of o-,m-,p-tolyl isomers

 

 

3967.19-10MG

Diphenyltolylphosphate - Mixture of o-,m-,p-tolyl isomers

 

On request

8777.9-1G

Isopropylated trisphenyl phosphate (Phenol, isopropylated, phosphate)

IPPP

 

8767-1G

Phenoxyterminated carbonate oligomer of tetrabromobisphenol A

 

 

8739.19-100MG

Phenyl/Tolyl phosphates - Mixture of analogues - with detailed CoA

 

On request

8769-1G

Polyphosphoric acids ammonium salt

APP

 

8768-1G

2,4,6-Tribromophenylterminated tetrabromobisphenol-A carbonate oligomer

 

 

1399.12-K-IO

Tri-n-butylphosphate

TBP

 

8026.6-K-IO

Triethylphosphate

TEP

 

3966.12-K-IO

Triisobutylphosphate

TiBP

 

1400.3-K-IO

Trimethylphosphate

TMP

 

3968.12

Trimethylpropanephosphate

 

Please inquire

8027.9-K-IO

Tri-n-propylphosphate

 

 

2138.18-K-IO

Triphenylphosphate

TPP

 

2209.6-100-ME

Tris-(aziridinyl)-phosphineoxide

TEPA

 

2209.6-K-ME

Tris-(aziridinyl)-phosphineoxide

TEPA

 

2209.6-10MG

Tris-(aziridinyl)-phosphineoxide

TEPA

 

2209.6-100MG

Tris-(aziridinyl)-phosphineoxide

TEPA

 

2209.6-500MG

Tris-(aziridinyl)-phosphineoxide

TEPA

 

2209.6-1G

Tris-(aziridinyl)-phosphineoxide

TEPA

 

8586.9-100MG

Tris(2,3-dibromopropyl)phosphate

TBPP

 

8586.9-1G

Tris(2,3-dibromopropyl)phosphate

TBPP

 

8436.6-1G

Tris(2-chloroethyl)phosphate

 

 

8457.9-1G

Tris(monochloropropyl)phosphate

TCPP

 

8774.9

Tris(2-chloropropyl)phosphate

 

Please inquire

8505.9-1G

Tris(1,3-dichloro-2-propyl)phosphate

 

 

8775.9-K-ME

Tris(2,3-dichloropropyl)phosphate

 

 

2135.21-K-IO

Tri-o-tolylphosphate

ToTP

 

2134.21-K-IO

Tri-m-tolylphosphate

TmTP

 

2136.21-K-IO

Tri-p-tolylphosphate

TpTP

 

2137.21-K-IO

Tritolylphosphate (isomer mixture) "Tricresylphosphate”

  TCP

 

 

 
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