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Biomarker Focus 41: Deuterated Tin Chlorides
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Organotin compounds are widely applied in the industry due
to their antibacterial and fungicidal properties.
Applications include preservation of wood, textiles,
leather and paper, and as disinfectants.
Due to their toxicity the use of trialkyltin compounds in
marine antifoulding paints is restricted.
The trialkyltin compounds are partly
degraded to the di- and monoalkyltin derivatives.
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New Internal standards for analysis of tinchlorides:
9126.4-K-IO Mono-n-butyltin-d9 trichloride, CD3CD2CD2CD2-Sn3+, 3Cl-
9127.12-K-IO Tri-n-butyl-d27 chloride, (CD3CD2CD2CD2)3-Sn+, Cl-
9129.6-K-IO Monophenyltin-d5 trichloride, C6D5-Sn3+,3Cl-
9128.18-K-IO Triphenyltin-d15 chloride, (C6D5)3-Sn+,Cl-
Avaliable as 1000¨¬g/mL in isooctane, 1 mL
Useful internal standard in the derivatization with sodium tetraethyl borate and use in ISO methods 17353 and 23161:
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Natives: |
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CH3CH2CH2CH2-Sn3+, 3Cl- (1983.4-K-5ME / 1G) ¡ú CH3CH2CH2CH2-Sn-(CH2CH3)3 (2119.10-K-IO) |
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(CH3CH2CH2CH2)3-Sn+, Cl- (1981.12-K-5ME / 1G) ¡ú (CH3CH2CH2CH2)3-Sn-CH2CH3 (1886.14-K-IO) |
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C6H5-Sn3+, 3Cl- (1987.6-K-5ME / 1G) ¡ú C6H5-Sn-(CH2CH3)3 (2118.12-K-IO) |
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(C6H5)3-Sn3+, Cl- (1985.18-K-5ME / 1G) ¡ú (C6H5)3-Sn-CH2CH3 (1887.20-K-IO) |
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Internal standards: |
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CD3CD2CD2CD2-Sn3+, 3Cl- (9126.4-K-IO) ¡ú CD3CD2CD2CD2-Sn-(CH2CH3)3 (9229.10-100-IO) |
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(CD3CD2CD2CD2)3-Sn+, Cl- (9127.12-K-IO) ¡ú (CD3CD2CD2CD2)3-Sn-CH2CH3 (9230.14-100-IO) |
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C6D5-Sn3+, 3Cl- (9129.6-K-IO) ¡ú C6D5-Sn-(CH2CH3)3 (9231.12-100-IO) |
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(C6D5)3-Sn3+, Cl- (9128.18-K-IO) ¡ú (C6D5)3-Sn-CH2CH3 (9232.20-100-IO) |
International standard methods
- ISO 17353:2004 Water Quality - Determination of selected organotin compounds -
Gas chromatographic method.
- ISO/DIS 23161.2:2007 Soil Quality - Determination of selected organotin compounds -
Gas chromatographic method.
As a unique source, Chiron offers standards for the derived analytes for use as calibration standards, in addition to the derivatizing agent and the common trialkyltin chloride pollutants.
PRODUCT OVERVIEW TINORGANICS:
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Tin-organics |
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Tin chlorides (common pollutants) |
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1983.4-K-5ME * |
Mono-n-butyltin trichloride |
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1982.8-K-5ME * |
Di-n-butyltin dichloride |
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1982.8-K-5IO |
Di-n-butyltin dichloride |
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1981.12-K-5ME * |
Tri-n-butyltin chloride |
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1981.12-K-5IO |
Tri-n-butyltin chloride |
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2497.16-K-IO * |
Tetra-n-butyltin |
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2487.8-K-ME * |
Mono-n-octyltin trichloride |
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2488.16-K-ME * |
Di-n-octyltin dichloride |
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2695.24-K-5ME |
Tri-n-octyltin chloride |
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2695.24-100MG |
Tri-n-octyltin chloride |
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1987.6-K-5ME * |
Monophenyltin trichloride |
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1986.12-K-5ME * |
Diphenyltin dichloride |
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1985.18-K-5ME * |
Triphenyltin chloride |
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1985.18-K-5IO |
Triphenyltin chloride |
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2489.18-500-ME * |
Tricyclohexyltin chloride |
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2489.18-K-ME |
Tricyclohexyltin chloride |
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1984.3-KIT-S |
Butyltin chlorides Kit (solutions, 1983.4, 1982.8, 1981.12) |
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1984.3-KIT-N |
Butyltin chlorides Kit (neat, 1983.4, 1982.8, 1981.12) |
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1988.3-KIT-S |
Phenyltin chlorides Kit (solutions, 1987.6, 1986.12, 1985.18) |
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1988.3-KIT-N |
Phenyltin chlorides Kit (neat, 1987.6, 1986.12, 1985.18) |
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3726.10-KIT |
Tin Chlorides Kit I (neat, 1983.4, 1982.8, 1981.12, 1987.6, 1986.12, 1985.18, 2487.8, 2488.16, 2695.24, 2489.18, includes all tin chloride analytes) |
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Internal standards (tin chlorides and tetralkyl) |
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1989.9-K-ME * |
Tri-n-propyltin chloride |
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2050.15-K-ME * |
Tri-n-pentyltin chloride |
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2490.12-K-IO * |
Tetra-n-propyltin |
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3956.15-K-IO * |
Tetra-n-pentyltin |
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2495.7-K-ME |
Mono-n-heptyltin trichloride |
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2495.7-100MG |
Mono-n-heptyltin trichloride |
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2495.7-K-IO |
Mono-n-heptyltin trichloride |
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2496.14-K-ME |
Di-n-heptyltin dichloride |
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2496.14-100MG |
Di-n-heptyltin dichloride |
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2496.14-K-IO |
Di-n-heptyltin dichloride |
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8556.14-KIT-S |
Tin Chlorides Kit II (solutions, 1983.4, 1982.8, 1981.12, 1987.6, 1986.12, 1985.18, 2487.8, 2488.16, 2695.24, 2489.18, 1989.9, 2050.15, 3956.15, 2495.14, includes all tin chloride analytes and internal standards) |
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8556.14-KIT-N |
Tin Chlorides Kit II (neat, 1983.4, 1982.8, 1981.12, 1987.6, 1986.12, 1985.18, 2487.8, 2488.16, 2695.24, 2489.18, 1989.9, 2050.15, 3956.15, 2495.14, includes all tin chloride analytes and internal standards) |
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Deuterated Internal Standard |
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8554.12-K-IO |
Tetra-n-propyltin-d7 (mono-n-propyl-d7) |
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8554.12-K-IOx5 |
Tetra-n-propyltin-d7 (mono-n-propyl-d7) |
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9126.4-K-IO |
Mono-n-butyltin-d9 trichloride |
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9127.12-K-IO |
Tri-n-butyltin-d27 chloride |
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9129.6-K-IO |
Monophenyltin-d5 trichloride |
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9128.18-K-IO |
Triphenyltin-d15 chloride |
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8555.19-S |
Organotin Analytes + Internal Standards, Solutions Kit (19 compounds, 19 vials, includes 1944.8 as neatand 8554.12 in solution) |
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8555.19-N |
Organotin Analytes + Internal Standards, Neat Kit (19 compounds, 19 vials, includes 1944.8 as neat and 8554.12 in solution) |
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Analytes ethyl derivatives |
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2119.10-K-IO |
Mono-n-butyltriethyltin |
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2120.12-K-IO |
Di-n-butyldiethyltin |
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1886.14-K-IO |
Ethyltri-n-butyltin |
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2492.14-K-IO |
Mono-n-octyltriethyltin |
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2491.20-K-IO |
Di-n-octyldiethyltin |
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8553.26-K-IO |
Ethyltri-n-octyltin |
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2498.20-K-IO |
Ethyltricyclohexyltin |
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2118.12-K-IO |
Monophenyltriethyltin |
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2117.16-K-IO |
Diphenyldiethyltin |
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1887.20-K-IO |
Ethyltriphenyltin |
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Internal standards ethyl derivatives |
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1955.11-K-IO |
Ethyltri-n-propyltin |
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2049.17-K-IO |
Ethyltri-n-pentyltin |
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2494.13-K-IO |
Mono-n-heptyltriethyltin |
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2493.18-K-IO |
Di-n-heptyldiethyltin |
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2023.14-KIT |
Ethylderivatives Kit (Ethylalkyl-/ Ethylaryltin Kit) |
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Deuterated Internal Standards ethyl derivatives |
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9229.10-100-IO |
Mono-n-butyltriethyltin-d9 (mono-n-butyl-d9) |
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9230.14-100-IO |
Ethyltri-n-butyltin-d27 (tri-n-butyl-d27) |
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9231.12-100-IO |
Monophenyltriethyltin-d5 (phenyl-d5) |
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9232.20-100-IO |
Ethyltriphenyltin-d15 (triphenyl-d15) |
* Also available in 1 g amount.
All Tin Monochlorides have a limites shelf life of 4 months from date of purchase.
Derivatizing Agent and Kits:
1944.8.1-1G Sodium tetraethyl borate (Derivatizing agent), 1 g
8555.19-KIT-S Organotin Analytes + Internal Standards, Solutions Kit (19 compounds, 19 vials,
includes 1944.8 as neat)
8555.19-KIT-N Organotin Analytes + Internal Standards, Neat Kit (19 compounds, 19 vials, includes 1944.8
as neat and 8554.12 in solution)
3726.10-KIT-N Tin Chlorides Neat KIT I (includes Analytes but not Internal Standards)
8556.14-KIT-S Tin Chlorides Neat KIT II (includes Internal Standards and Analytes in solution)
8556.14-KIT-N Tin Chlorides Neat KIT II (includes Internal Standards and Analytes as neat)
2023.14-KIT Ethyl derivatives Kit, Solutions
2024.33-KIT-S Organotin Analysis Solutions KIT (includes all the compounds, includes 1944.8 as neat)
2024.33-KIT-N Organotin Analysis Neat KIT (includes all the compounds, includes 1944.8 as neat)
See also BMF 24-2 for info on Deuterated alkyl - and aryltin compounds.
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